Publication | Closed Access
Rapid Defunctionalization of Carbonyl Group to Methylene with Polymethylhydrosiloxane−B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>
120
Citations
28
References
2002
Year
High YieldsOrganic Material ChemistryChemical EngineeringNovel OrganocatalystsRapid ConditionsEngineeringAliphatic Carbonyl CompoundsCatalytic SynthesisOrganic ChemistryOrganometallic CatalysisCatalysisChemistrySynthetic ChemistryRapid Defunctionalization
The polymethylhydrosiloxane-B(C(6)F(5))(3) combination is found to be a versatile carbonyl defunctionalization system under mild and rapid conditions. For the first time, B(C(6)F(5))(3) has been used as a nonconventional Lewis acid catalyst to activate PMHS. Aromatic and aliphatic carbonyl compounds were effectively reduced to give the corresponding alkanes in high yields.
| Year | Citations | |
|---|---|---|
Page 1
Page 1