Acetylene Adsorption on CPO‐27‐M Metal–Organic Frameworks (M=Fe, Co and Ni)

Abstract

MOFs as acetylene adsorbents: The adsorption of acetylene on the isostructural metal–organic frameworks CPO-27-M (where M=Fe, Co and Ni) is studied by FTIR, UV/Vis spectroscopy, and calorimetric isotherm measurements. The results show that M–O pairs act as the adsorption sites in these materials and that the Ni analogue is the strongest acetylene adsorbent of the series. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.