Concepedia

Carbenoid or Lithium Complex of a Carbanion? Synthesis and Structure of (Me<sub>3</sub>Si)<sub>2</sub>CP(aryl)C(Cl)Li(thf)<sub>3</sub> and LiCl Elimination To Give the Phosphirene

Edgar Niecke, P. Becker, Martin Nieger, Dietmar Stalke, Wolfgang W. Schoeller

Angewandte Chemie International Edition in English · 1995 · 69 citations · 24 references

DOI

Concepts

Abstract

The transition to the carbanion is represented by the structure of the carbenoid 2, which is accessible from 1. The solid-state structures of 1 and 2 have been determined. Compound 2 is converted into the phosphirene 3 by elimination of LiCl.

References

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