Concepedia

Mechanistic Surprises in the Gold(I)‐Catalyzed Intramolecular Hydroarylation of Allenes

Dieter Weber, Michael A. Tarselli, Michel R. Gagné

Angewandte Chemie International Edition · 2009 · 283 citations · 37 references

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Concepts

Abstract

Two for the show: Mechanistic studies on the cyclization of allenic arenes indicated that the catalyst rests at a dinuclear bridging vinyl structure, which was isolated and its reactivity examined.

References

37

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A. Stephen K. Hashmi, Graham J. Hutchings · Angewandte Chemie International Edition · 2006 · 3.4K citations

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Catalytic Carbophilic Activation: Catalysis by Platinum and Gold π Acids

Alois Fürstner, Paul Davies · Angewandte Chemie International Edition · 2007 · 2.3K citations

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Phosphine Gold(I) Bis-(trifluoromethanesulfonyl)imidate Complexes as New Highly Efficient and Air-Stable Catalysts for the Cycloisomerization of Enynes

Nicolas Mézailles, Louis Ricard, Fabien Gagosz · Organic Letters · 2005 · 687 citations

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Recent Developments in Enantioselective Gold(I) Catalysis

Ross A. Widenhoefer · Chemistry - A European Journal · 2008 · 566 citations

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Coordination Chemistry of Ene‐1,1‐diamines and a Prototype “Carbodicarbene”

Alois Fürstner, Manuel Alcarazo, Richard Goddard et al. · Angewandte Chemie International Edition · 2008 · 460 citations

, , +11