Reversible Dihydrogen Activation in Cationic Rare‐Earth‐Metal Polyhydride Complexes

Abstract

In or out? A quadruply hydride-bridged dilutetium complex releases dihydrogen under CH bond activation of one of the methyl groups of the ligand. The resulting trihydrido complex readily takes up dihydrogen (see scheme). As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.