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M(CO)<sub>6</sub>–RCl<sub>n</sub>–hν catalysts (M = W, Mo; RCl<sub>n</sub>= PhCCl<sub>3</sub>, Ph<sub>2</sub>CCl<sub>2</sub>): new catalyst systems for the metathesis polymerization of substituted acetylenes and cycloalkenes
14
Citations
6
References
1996
Year
Materials ScienceChemical EngineeringEngineeringMetathesis PolymerizationAlkene Metathesis6–Rcln-hν SystemsSubstituted AcetylenesNew Catalyst SystemsOrganic ChemistryOrganometallic CatalysisCatalysisHomogeneous CatalysisChemistryMolecular CatalysisEffective CatalystsRcln= Phccl3Catalytic SynthesisPolymers
The M(CO)6–RCln-hν systems (M = W, Mo; RCln= PhCCl3, Ph2CCl2) work as effective catalysts for the polymerizations of substituted acetylenes and norbornene to provide high molecular weight polymers in good yields, where RCln are sufficient in catalytic amounts unlike CCl4.
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