Chemical Communications · 2015 · 221 citations · 29 references
Natural SciencesChemical EngineeringChemistryBiocatalysisCatalysisReaction EngineeringBio-based MaterialsCatalytic MaterialsCatalytic Reaction EngineeringMetal SulfidesSulfide MineralogySulfide MineralsCarbon Dioxide Reduction CatalysisIron SulfidesIron-sulfur ChemistryIron-sulfur Mineral ChemistryMetal Sulfide CatalysisMineral-catalyzed ReactionsSulfide Mineral ReactivitySulfide-oxidizing Microorganisms
The mineral greigite presents similar surface structures to the active sites found in many modern-day enzymes. We show that particles of greigite can reduce CO2 under ambient conditions into chemicals such as methanol, formic, acetic and pyruvic acid. Our results also lend support to the Origin of Life theory on alkaline hydrothermal vents.
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Surface chemistry of carbon dioxide
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