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A Novel Example of Metal-Mediated Aromatic Thiolation in a Ruthenium Complex. Crystal Structure of Ru<sup>II</sup>(SC<sub>6</sub>H<sub>4</sub>NNC<sub>6</sub>H<sub>4</sub>N)<sub>2</sub>
97
Citations
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References
1996
Year
Inorganic CompoundInorganic ChemistryCrystal StructureEngineeringHeterocyclicBiochemistryNatural SciencesCoordination ComplexRuthenium ComplexMetal-mediated Aromatic ThiolationMolecular ComplexCompound 3ChemistryCrystallographyInorganic SynthesisUnusual Product
ctc-Ru(L)2(Cl)2, 1 [L = pyridine-2-azobenzene], reacts with EtOCS2K to give an unusual product, 3, where the ortho-carbon atom of the pendant phenyl ring of each L is selectively thiolated. Crystal structure and spectra of compound 3 are reported.
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