Angewandte Chemie International Edition · 2001 · 48 citations · 21 references
Natural SciencesChemistryMaterials ScienceCrystal StructureInorganic ChemistrySolid-state ChemistryCoordination ChemistryCrystal ChemistryInorganic SynthesisMetal-ligand BondingTransition Metal ChemistryTransition Metal ComplexesBidentate Ligand BindingLanthanide ComplexesLanthanide Coordination ChemistryLewis AcidityLigand DesignLigand Effects On ReactivitySingle-crystal DiffractionSingle-crystal X-ray Diffraction
Functioning as a bidentate ligand toward Lewis acids, dibismuthane forms bisadducts of the type [R3M]2[Bi2R] with R3M=tBu3Al (1) and tBu3Ga (2; structure depicted; R′=Et), which were characterized by single-crystal X-ray diffraction.
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