Concepedia

Unprecedented Migration of a Methyl Group in 2-(2‘,6‘-Dimethylphenylazo)-4-methylphenol Mediated by Ruthenium

Sumon Nag, Parna Gupta, Ray J. Butcher, Samaresh Bhattacharya

Inorganic Chemistry · 2004 · 48 citations · 23 references

DOI

Concepts

Abstract

An unprecedented chemical transformation of 2-(2',6'-dimethylphenylazo)-4-methylphenol has been observed upon its reaction with [Ru(PPh(3))(2)(CO)(2)Cl(2)] whereby the methyl group at the 2' position migrates to the 4' or 6' position.

References

23

Abnormal Ligand Binding and Reversible Ring Hydrogenation in the Reaction of Imidazolium Salts with IrH<sub>5</sub>(PPh<sub>3</sub>)<sub>2</sub>

Stephan Gründemann, Anes Kovacevic, Martin Albrecht et al. · Journal of the American Chemical Society · 2002 · 333 citations

, , +17

Advances in Metal Chemistry of Quinonoid Compounds:  New Types of Interactions between Metals and Aromatics

Arkadi Vigalok, David Milstein · Accounts of Chemical Research · 2001 · 145 citations

, , +17

Unusual Coordination Mode of Thiosemicarbazone Ligand. Synthesis, Structure, and Redox Properties of Some Ruthenium and Osmium Complexes

Falguni Basuli, Michael Ruf, Cortlandt G. Pierpont et al. · Inorganic Chemistry · 1998 · 129 citations

, , +10

Comparison of Steric and Electronic Requirements for C−C and C−H Bond Activation. Chelating vs Nonchelating Case

Boris Rybtchinski, Stephan Oevers, Michael Montag et al. · Journal of the American Chemical Society · 2001 · 118 citations

, , +15

Chemical Control on the Coordination Mode of Benzaldehyde Semicarbazone Ligands. Synthesis, Structure, and Redox Properties of Ruthenium Complexes

Falguni Basuli, Shie‐Ming Peng, Samaresh Bhattacharya · Inorganic Chemistry · 2001 · 108 citations

, , +16