CO2 Foaming of Polymer Nanocomposite Blends

Abstract

Nanoparticles are suitable to nucleate small foam cells and simultaneously reinforce the thin foam cell walls. In this paper, it is found that the foam morphology and the physical properties are greatly influenced by the dispersion of nanoclay, the clay surface modification, and the nanocomposite blend morphology. The addition of nanoclay to polystyrene (PS) strongly affects the nucleation of foam bubbles, especially after exfoliation and proper surface modification. CO2 appears to nucleate on the solid clay surface with a CO2-affinitive surface modifier. PS/(PMMA/MHABS) nanocomposite blends composed of polystyrene and poly(methyl methacrylate)/nanoclay exfoliated nanocomposite show an unexpected trend that bubble nucleation inversely correlates with domain size, where the bigger PMMA/MHABS domains are significant in nucleating more bubbles. The total influence volume, formed by the CO2 diffusion from the PMMA/MHABS phase to the PS phase where CO2 concentration decreases from a high value in the former to a low value in the latter, is related to the domain size and determines the nucleation efficiency in the PS phase. The physical properties of PS nanocomposites exhibit unique behaviour in the presence of CO2.