Concepedia

A palladium-catalysed stannole synthesis: development and mechanism

Jochen Krause, Christian Pluta, Klaus‐R. Pörschke, Richard Goddard

Journal of the Chemical Society Chemical Communications · 1993 · 33 citations · 7 references

DOI

Concepts

Abstract

A palladium-catalysed stannole synthesis is described and its mechanism elucidated by the synthesis of several conceivable intermediates, which have been fully characterized (NMR, X-ray structure analyses).

References

7

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Stabilisation of metals in a low co-ordinative environment using the bis(trimethylsilyl)methyl ligand; coloured Sn II and Pb II alkyls, M[CH(SiMe3)2]2

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Subvalent Group 4B metal alkyls and amides. Part 9. Germanium and tin alkene analogues, the dimetallenes M<sub>2</sub>R<sub>4</sub>[M = Ge or Sn, R = CH(SiMe<sub>3</sub>)<sub>2</sub>]: X-ray structures, molecular orbital calculations for M<sub>2</sub>H<sub>4</sub>, and trends in the series M<sub>2</sub>R′<sub>4</sub>[M = C, Si, Ge, or Sn; R′= R, Ph, C<sub>6</sub>H<sub>2</sub>Me<sub>3</sub>-2,4,6, or C<sub>6</sub>H<sub>3</sub>Et<sub>2</sub>-2,6]

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(R2PC2H4PR2)Pd0 alkene and ethyne complexes

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Homoleptic, three-co-ordinate group 8c noble metal(0) complexes having Ge<sup>II</sup>or Sn<sup>II</sup>ligands, [M{M′(NR<sub>2</sub>)<sub>2</sub>}<sub>3</sub>](M = Pd or Pt, M′= Ge or Sn, R = SiMe<sub>3</sub>), and the X-ray structure of one of them (M = Pd, M′= Sn)

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