Concepedia

Synthesis of 9,9′-<i>Bis</i>(m-Carboranyl) upon Catalytic Decomposition of 9,9′-<i>Bis</i>(m-Carboranyl) Mercury under Influence of (PPh<sub>3</sub>)<sub>3</sub>RhCl

L. I. Zakharkin, N. Yu. Krainova, I. V. Pisareva, V. A. Antonovich

Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry · 1985 · 11 citations · 4 references

DOI

Concepts

Abstract

Abstract A simple method is reported for the synthesis of 9,9-bis(m-carboranyl) from 9,9′-bis (m-carboranyl) mercury upon its decomposition under the influence of catalytic amounts of (PPh3)3RhCl in HMPA. Under these conditions, 9-m-carboranylmercury chloride easily forms 9-chloro-m-carborana and metallic mercury. A simple method for symmetrization of 9-o- and 9-m-carooranylmercury chloride into 9,9′-bis(o- and m-carboranyl)mercury under influence of sodium stannite in an alkaline medium was elaborated.

References

4

Mercury in organic chemistry. 11. Synthesis of symmetrical 1,3-dienes and biaryls via rhodium catalyzed dimerization of vinyl- and arylmercurials

Richard C. Larock, J. C. BERNHARDT · The Journal of Organic Chemistry · 1977 · 69 citations

, , +6

The mercuration of ortho- and meta-carboranes

Vladimir I. Bregadze, V. Ts. Kampel', N. N. Godovikov · Journal of Organometallic Chemistry · 1976 · 57 citations

, , +2

Linked and mercury-bridged nido-carboranes. High-yield synthesis of .mu.,.mu.'-[(CH3)2C2B4H5]2Hg, conversion to 5,5'-[(CH3)2C2B4H5]2, cleavage, and oxidative addition of benzene. Synthesis of .mu.,.mu.'-(B5H8)2Hg

Narayan S. Hosmane, Russell N. Grimes · Inorganic Chemistry · 1979 · 46 citations

, , +6

RhCl(PPh3)3-catalyzed Coupling of Diorganomercurials

Kentaro Takagi, Naomi Hayama, Tadashi Okamoto et al. · Bulletin of the Chemical Society of Japan · 1977 · 34 citations

, , +13