Concepedia

Retention of regiochemistry of monosubstituted allyl acetates in the ruthenium catalysed allylic alkylation with malonate anion

Motoi Kawatsura, Fumio Ata, Shuichi Hayase, Toshiyuki Itoh

Chemical Communications · 2007 · 43 citations · 39 references

DOI

Concepts

Abstract

In the RuCl2(p-cymene)/PPh3 catalysed regioselective allylic alkylation of monosubstituted allyl acetates with malonate anion, the selective substitution at the position originally substituted with acetate was observed.

References

39

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