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Efficient Synthesis of Quinoxalines in the Ionic Liquid 1-<i>n</i>-Butylimidazolium Tetrafluoroborate ([Hbim]BF<sub>4</sub>) at Ambient Temperature
48
Citations
22
References
2008
Year
Materials ScienceInorganic ChemistryChemical EngineeringIonic LiquidEngineeringDerivative (Chemistry)Ionic ConductorAbstract Quinoxaline DerivativesQuinoxaline DerivativesFluorous SynthesisOrganic ChemistryEfficient SynthesisChemistryHeterocycle ChemistryAmbient TemperatureChemical DerivativeSynthetic Chemistry
Abstract Quinoxaline derivatives have been synthesized in excellent yields using an ionic liquid (IL) (viz., 1-n-butylimidazolium tetrafluoroborate) as a reaction medium as well as promoter from various 1,2-diketones and aryl-1,2-diamines. The process is general for the synthesis of quinoxaline derivatives from aromatic as well as aliphatic-1,2-diketones. The advantages of the present method are ambient reaction temperature, simplicity of operation, high yields of products, the recyclability of the IL, and ecofriendly nature of the reaction medium.
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