Quantum Dot Exciton Dynamics through a Nanoaperture: Evidence for Two Confined States

Abstract

Excitons confined to CdSe/ZnSe self-assembled quantum dots are probed through a nanoaperture using time-resolved photoluminescence. Significant evidence is shown that two different electronic states are associated with these dots, with binding energies which differ by an order of magnitude. The first has a short 450 ps lifetime, exhibits a relatively broad emission line, and persists nearly to room temperature; the second exhibits a long $(>4\mathrm{ns})$ lifetime and is responsible for the sharp $(\ensuremath{\sim}100\ensuremath{\mu}\mathrm{eV})$ lines seen at low temperatures $(<60\mathrm{K})$. These results are completely unlike those seen in III-V dots, and reveal the complexity of the electronic structure in CdSe dots.