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The first example of catalytic N-oxidation of tertiary amines by tungstate-exchanged Mg–Al layered double hydroxide in water: a green protocol
52
Citations
12
References
2001
Year
Materials ScienceRoom TemperatureChemical EngineeringOxygen Reduction ReactionGreen ProtocolEngineeringGreen ChemistryDouble HydroxideHeterogeneous CatalysisOrganic ChemistryCatalysisChemistryCatalyst PreparationCatalytic ProcessGreen ProcessCatalytic SynthesisCatalytic N-oxidation
A green process, using a recyclable tungstate-exchanged Mg-Al layered double hydroxide (LDH-WO4(2-)) heterogenised catalyst and aqueous H2O2 oxidant in water, leads to N-oxidation of aliphatic tert-amines to amine N-oxides in quantitative yields, at a high rate at room temperature.
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