Electroconductive Porous Coordination Polymer Cu[Cu(pdt)₂] Composed of Donor and Acceptor Building Units

Abstract

We synthesized a new porous coordination polymer Cu[Cu(pdt)2], which shows relatively high electrical conductivity (6 x 10(-4) S cm(-1) at 300 K) by the introduction of electron donors and acceptors as building units. This compound is applicable as a porous electrode with high power density. In addition, this compound forms a triangular spin lattice and shows spin frustration.