Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics · 1994 · 67 citations · 11 references
Natural SciencesChemistryPhysicsChemical KineticsFluid DynamicsTransport PhenomenaBoundary-layer TheoryCapillary WavesChemical Reaction KineticsConvection DynamicsReaction-diffusion SystemsWave PropagationFluid ModelsReaction Front PropagationTwo-way Slab SystemsWave Fronts
We present a theory for the vertical propagation of chemical waves near the onset of convection. Fluid motion, coupled to a standard reaction-diffusion mechanism for chemical wave propagation, determines the speed and shape of the reaction front in a two-dimensional slab. Our model is compared with experiments in capillary tubes. For tilted and horizontal tubes, fluid motion is always present with a corresponding increase in front speed.
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