“ONE POT” DOUBLE CARBON–CARBON LINKAGES ON THE NEIGHBORING CARBONS VIA AN ENOL ETHER AS A REACTION INTERMEDIATE

Abstract

Abstract Two new “one pot” double alkylation reactions, 1) allylation of α,β-enones with allylsilanes and subsequent reaction with electrophiles, and 2) acylation of α-siloxyallylsilanes with acid halides followed by consecutive introduction of other electrophiles on the neighboring carbon atom, are reported.