Chemical Communications · 2007 · 54 citations · 55 references
Cross-coupling ReactionEngineeringHeterocyclicCatalytic AmountsStrained IodoOrganic ChemistryOrganometallic CatalysisCatalysisChemistryRuthenium-catalyzed Enyne CycloisomerizationHalogenationCyclobutene DerivativesEnantioselective SynthesisBiomolecular Engineering
Enynes bearing an iodide (bromide) at their alkyne terminus react with catalytic amounts of [Cp*Ru(MeCN)3]PF6 in DMF to give strained iodo(bromo)cyclobutene derivatives in good to excellent yields.
55
A. Stephen K. Hashmi, Graham J. Hutchings · Angewandte Chemie International Edition · 2006 · 3.4K citations
Iron-Catalyzed Cross-Coupling Reactions
Alois Fürstner, Andreas Leitner, Marı́a Méndez et al. · Journal of the American Chemical Society · 2002 · 809 citations