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Isolation and X-ray structure of [(µ-H)Ru<sub>3</sub>(CO)<sub>9</sub>(µ<sub>3</sub>-PhNCPh)], the catalytically active cluster in Ru<sub>3</sub>(CO)<sub>12</sub>-catalysed transfer hydrogenation of benzylideneaniline
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1987
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Inorganic ChemistryChemical EngineeringTransfer HydrogenationEngineeringActive ClusterX-ray StructureHeterogeneous CatalysisOrganometallic CatalysisCatalysisMolecular CatalysisHydrogenChemistryCatalytic Synthesis12-Based Catalytic System
(µ-H)Ru3(CO)9(µ3-PhNCPh)(1) has been isolated from an Ru3(CO)12-based catalytic system for the transfer hydrogenation of benzylideneaniline and found to be catalytically active; the X-ray structure of (1) is reported.