Concepedia

A well-defined silica-supported aluminium alkyl through an unprecedented, consecutive two-step protonolysis–alkyl transfer mechanism

Jérémie D. A. Pelletier, Jeff Espinas, Nghiem Vu, Sébastien Norsic, Anne Baudouin, Laurent Delevoye, Julien Trébosc, Erwan Le Roux, Catherine C. Santini, Jean‐Marie Basset,

Chemical Communications · 2011 · 56 citations · 27 references

DOI

Concepts

Abstract

Impregnation of [(AliBu(3))(Et(2)O)] on partially dehydroxylated SBA-15 affords a mesoporous material bearing the well-defined single site surface aluminium species [(≡SiO)(2)Al(iBu)(Et(2)O)].

References

27

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, , +12

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Surface organometallic chemistry in the chemical vapor deposition of aluminum films using triisobutylaluminum: .beta.-hydride and .beta.-alkyl elimination reactions of surface alkyl intermediates

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Infrared and gravimetric study of an aerosil and a precipitated silica using chemical and hydrogen/deuterium exchange probes

B. A. Morrow, Andrew McFarlan · Langmuir · 1991 · 152 citations

, , +14

Chemical vapour deposition of nitride thin films

David M. Hoffman · Polyhedron · 1994 · 151 citations

, , +14