Oxarhodaborane chemistry: the formation of [µ-9,9′-O-{5-(η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)-nido-5-RhB<sub>9</sub>H<sub>12</sub>}<sub>2</sub>] and [7-(η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)-10-(NEt<sub>3</sub>)-nido-7, 12-RhOB<sub>10</sub>H<sub>10</sub>] from [nido-(η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)RhB<sub>10</sub>H<sub>13</sub>Cl] - Concepedia

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Oxarhodaborane chemistry: the formation of [µ-9,9′-O-{5-(η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)-nido-5-RhB<sub>9</sub>H<sub>12</sub>}<sub>2</sub>] and [7-(η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)-10-(NEt<sub>3</sub>)-nido-7, 12-RhOB<sub>10</sub>H<sub>10</sub>] from [nido-(η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)RhB<sub>10</sub>H<sub>13</sub>Cl]

35

Citations

9

References

1990

Year

Evert J. Ditzel, Xavier L. R. Fontaine, Hayat Fowkes, N. N. Greenwood, John F. Kennedy, Peter MacKinnon, Zhu Sisan, Mark Thornton‐Pett

Journal of the Chemical Society Chemical Communications

Inorganic CompoundInorganic ChemistryChemical EngineeringEngineeringStructure ElucidationAnalytical Chemistryµ-9,9′-Oxo-bridged BisOrganometallic CatalysisMain Group ChemistryChemistryWhereas TreatmentInorganic SynthesisSilica ResultsOxarhodaborane Chemistry

Abstract

Chromatography in air on silica of the nido eleven-vertex metallaborane [(η5-C5Me5)RhB10H13Cl]2, yields the µ-9,9′-oxo-bridged bis(nido-5-rhodadecaboranyl) species [{(η5-C5Me5)RhB9H12}2O]3, whereas treatment with NEt3 before exposure to air and chromatography on silica results in the novel contiguous nido twelve-vertex oxarhodadecaborane [7-(η5-C5Me5)10-(NEt3)-nido-7,12-RhOB10H10]4.

References

	Year	Citations

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