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A new class of five-co-ordinate titanium complexes containing a polyfunctional amido ligand. Crystal structure of [TiBr2{CH(2-C5H4N)(CH2NSiMe3)2}]
28
Citations
9
References
1993
Year
Materials ScienceInorganic ChemistryCrystal StructureTitanium Amido HalidesEngineeringCoordination ComplexPolyfunctional Amido LigandOligonuclear ComplexesNew ClassMolecular ComplexChemistryCrystallographyInorganic SynthesisBiomolecular EngineeringInorganic Compound
A new class of titanium amido halides containing a tripodal ligand with two amido and one pyridyl-N function, which are potential building blocks for the synthesis of oligonuclear complexes, has been prepared; a single-crystal X-ray structure analysis of [TiBr2{CH(2-C5H4N)(CH2NSiMe3)2}] has established its five-co-ordinate molecular geometry.
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