A heterotrimetallic 3d–3d′–4f single chain magnet constructed from anisotropic high-spin 3d–4f nodes and paramagnetic spacers

Abstract

By connecting [LCuTb](3+) nodes with [Fe(CN)₆]³⁻ spacers a 1-D coordination polymer with slow relaxation of magnetization is obtained (L²⁻ is the N,N'-propylene-bis(3-methoxysalicylideneiminato) anion).