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Synthesis, crystal and molecular structure of calcium oxo ethoxide, [Ca<sub>6</sub>(µ<sub>4</sub>-O)<sub>2</sub>(µ<sub>3</sub>-OEt)<sub>4</sub>(OEt)<sub>4</sub>]·14EtOH
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Citations
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References
1993
Year
Materials ScienceInorganic ChemistryEthanol SolvateEngineeringBiochemistryCalcium OxoNatural SciencesX-ray DiffractionCalcium AluminateChemistryInorganic MaterialCrystallographyCalcium Oxo EthoxideInorganic SynthesisInorganic Compound
The hexanuclear complex of calcium oxo ethoxide ethanol solvate, [Ca6O2(OEt)8]·14EtOH 1 has been isolated after the prolonged refluxing of an ethanol solution of calcium ethoxide in the presence of the oxygen in air and studied by X-ray diffraction; the metal-oxygen framework is built of two [Ca4O4] cubes sharing a common [Ca2O2] face, which involves both oxo groups.
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