Nematic Ordering of Suspensions of Charged Anisotropic Colloids Detected by ²³Na Nuclear Magnetic Resonance

Abstract

A detailed line shape analysis of 23 Na nuclear magnetic resonance spectra within dense suspensions (12% vol/vol) of Laponite clay exhibits a macroscopic ordering of these charged anisotropic colloids within a nematic phase. The angular variation of the order parameter limits to 20% of the maximum amount of disorder in these dense suspensions. By contrast, dilute Laponite suspensions (1−4% vol/vol) remain isotropic while the variation of 23 Na relaxation rates over a broad range of frequencies indicates a local ordering of the clay platelets within microdomains of the same spatial extent than the particle diameter (300 Å).