Concepedia

The structures of solvent-separated naphthalene and anthracene radical anions

Hans Bock, Claudia Arad, Christian Näther, Zdeněk Havlas

Journal of the Chemical Society Chemical Communications · 1995 · 42 citations · 13 references

DOI

Concepts

Abstract

Reduction of naphthalene and anthracene in diglyme, a thermodynamically favourable chelate ether for Na+ solvation, with sodium metal gave the crystalline solvent-separated radical anion salts, [C10H8·–][Na+(diglyme)2] and [C14H10·–][Na+(diglyme)2] whose structures were determined.

References

13

Temperature dependence of thermal motion in crystalline naphthalene

C.P. Brock, Jack D. Dunitz · Acta Crystallographica Section B · 1982 · 285 citations

, , +12

Temperature dependence of thermal motion in crystalline anthracene

C.P. Brock, J. D. Dunitz · Acta Crystallographica Section B Structural Science · 1990 · 232 citations

, , +14

Distorted Molecules: Perturbation Design, Preparation and Structures

Hans Bock, Klaus Ruppert, Christian Näther et al. · Angewandte Chemie International Edition in English · 1992 · 168 citations

, , +12

The HMO-model and its application

Wj · Journal of Molecular Structure · 1977 · 136 citations

, , +1

Ether‐Solvated Sodium Ions in Salts Containing π‐Hydrocarbon Anions: Crystallization, Structures, and Semiempirical Solvation Energies

Hans Bock, Christian Näther, Zdeněk Havlas et al. · Angewandte Chemie International Edition in English · 1994 · 65 citations

, , +16