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A new type of low-temperature molecular metal based on [Ni(dmit)2] anions (H2dmit = 4,5-dimercapto-1,3-dithiole-2-thione)
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1989
Year
EngineeringNew TypeChemistryMetal Complex AnionsElectronic StructureInorganic CompoundSemiconductor TransitionCharge Carrier TransportMaterials ScienceInorganic ChemistryPhysicsPhysical ChemistrySemiconductor MaterialQuantum ChemistryInorganic SynthesisTransition Metal ChalcogenidesMolecular Metal ConductorsLow-temperature Molecular MetalNatural SciencesApplied Physics
In contrast to previously studied molecular metal conductors based on metal complex anions, studies of the variation with temperature of the conductivity of K0.4[Ni(dmit)2] show no metal to semiconductor transition down to 20 K.