Influence of chemical modification on tribological properties of elastomers

Abstract

Abstract Physical properties of surface modified synthetic elastomers were studied to understand the factors that reduce friction and provide advantages in practical use. Bromination, iodination, sulfonation, and chlorination were investigated. The coefficient of friction μ was measured using a modified version of the pin‐on‐disc apparatus. The surface energy, morphology, mechanical properties, and extent of chemical modification were also measured. An increased stiffness and microroughness were found to correlate with changes in the coefficient of friction. Sulfonation (100% H 2 SO 4 ) was found to be the most effective and universally acceptable method of chemical treatment from a tribological point of view. © 1995 John Wiley & Sons, Inc.