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The Structures of Tris(8‐dimethylaminol‐naphthyl)phosphane and Tris[2‐(dimethylaminomethyl)phenyl]phosphane: Crystallographic Evidence of Seven‐Coordinate Phosphorus
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References
1993
Year
Crystal StructureEngineeringCrystallographic EvidenceMolecular BiologySeven‐coordinate PhosphorusChemistryPhosphanes 1Inorganic CompoundP AtomPhosphoreneBiophysicsInorganic ChemistryAtomic PhysicsPhysical ChemistryQuantum ChemistryCrystallographyCrystal Structure DesignNatural SciencesRigid Phosphane 1
A pseudo seven-coordinate central phosphorus atom is observed in the phosphanes 1 and 2. In solution this coordination is retained in the rigid phosphane 1, whereas in 2 an equilibrium exists between the opened and closed forms; as a result, MeI reacts with 1 at the P atom, but with 2 at the N atom.
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