Exchange Adsorption of Trace Quantities of Cadmium in Soils Treated with Calcium and Sodium: A Reappraisal

R. P. Milberg, D. L. Brower, J. V. Lagerwerff

Soil Science Society of America Journal · 1978 · 17 citations · 0 references

Concepts

Abstract

Abstract Cadmium was selectively adsorbed over Ca in Cecil, Winsum, and Yolo soils with up to 1.7% of the total cation exchange capacity occupied by Cd. Selectivity was greatest in Yolo and least in Cecil. Effects of undissociated Cd in solution were minor. Separation factors ( K s ) decreased with increasing exchangeable Cd. Reexamination of Cd‐Na exchange revealed that anomalous earlier results were due to the dispersion of organic matter during treatment with Na 2 CO 3 in the preparation of Na‐saturated soils. Na‐Cd exchange was normal where organic matter loss was prevented.