Concepedia

Enantioselective hydroformylation with the chiral bidentate P,N-ligand 2-[1-(1S,2S,5R)-(–)menthoxydiphenylphosphino]pyridine cationic rhodium(<scp>I</scp>) complexes

Carmela Grazia Arena, F. Nicolò, Dario Drommi, Giuseppe Brunò, Felice Faraone

Journal of the Chemical Society Chemical Communications · 1994 · 49 citations · 11 references

DOI

Concepts

Abstract

Cationic rhodium(I) complexes containing the new chiral bidentate P,N ligand 2-[1-(1S,2S,5R)-(–)menthoxydiphenylphosphino]pyridine are prepared and used successfully in the enantioselective hydroformylation of olefinic substrates, styrene, 2-vinylnaphthalene, methylacrylate and vinylacetate.

References

11

Highly enantioselective hydroformylation of olefins catalyzed by new phosphine phosphite-rhodium(I) complexes

Nozomu Sakai, Satoshi Mano, Kyoko Nozaki et al. · Journal of the American Chemical Society · 1993 · 468 citations

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Asymmetric hydroformylation catalyzed by homogeneous and polymer-supported platinum complexes containing chiral phosphine ligands

G. PARRINELLO, J. K. Stille · Journal of the American Chemical Society · 1987 · 293 citations

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The asymmetric hydroformylation in the synthesis of pharmaceuticals

C. BOTTEGHI, Stefano Paganelli, A. Schionato et al. · Chirality · 1991 · 198 citations

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Rhodium catalysed asymmetric hydroformylation with chiral diphosphite ligands

Godfried J. H. Buisman, Paul C. J. Kamer, Piet W. N. M. van Leeuwen · Tetrahedron Asymmetry · 1993 · 168 citations

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Asymmetric hydroformylation of 1,2-disubstituted olefins catalysed by chiral phosphinephosphite–rhodium(<scp>I</scp>) complexes

Nozomu Sakai, Kyoko Nozaki, Hidemasa Takaya · Journal of the Chemical Society Chemical Communications · 1994 · 132 citations

, , +7