High birefringence lateral difluoro phenyl tolane liquid crystals

Abstract

Four laterally difluorinated phenyl tolane liquid crystals were synthesised and their physical properties evaluated. These compounds exhibit a fairly small heat fusion enthalpy (ΔH ∼ 12.56 kJ mol−1), which is favourable for mixture formulations. For comparison, four lateral difluoro cyclohexane tolane homologues are also studied. We doped 10 wt% of each compound into a commercial negative mixture N1 and measured the birefringence, visco-elastic coefficient and figure of merit. Birefringence varies very little between homologues, but the visco-elastic coefficient increases as alkyl chain length increases. The refractive indices of these guest–host mixtures at 1550 nm are also measured.