Langmuir · 2008 · 63 citations · 4 references
Natural SciencesElectrical EngineeringElectroanalytical MethodsElectrochemistryHydrogeologyElectrochemical Energy StorageElectrochemical KineticsElectrode KineticsElectrode-electrolyte InterfacesGalvanic CellsSurface ChargeCharge Storage MechanismsCharge Transfer At ElectrodesCurrent-potential RelationshipsPh DynamicsPh GradientsPh-dependent Charge
Large pH gradients can develop in water when current is passed between immersed electrodes. These gradients represent real charge separation that persists for minutes after power removal, and the stored charge can be largely recovered, indicating that water can store and release substantial amounts of charge.
Previous work from this and other laboratories has demonstrated large pH gradients in water. Established by passing current between immersed electrodes, pH gradients between electrodes were found to disappear slowly, persisting for tens of minutes after the current had been turned off. We find here that these pH gradients reflect a genuine separation of charge: at times well after disconnection of the power supply, current could be drawn through a resistor placed between the charging electrodes or between pairs of electrodes positioned on either side of the midline between original electrodes. In some experiments, it was possible to recover the majority of charge that had been imparted to the water. It appears, then, that water has the capacity to store and release substantial amounts of charge.
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Electrochemical methods, fundamentals and applications
D.A. Aikens · Journal of Chemical Education · 1983 · 3.2K citations
Visualization of Charge-Carrier Propagation in Water
A. N. Klimov, Gerald H. Pollack · Langmuir · 2007 · 25 citations