Concepedia

The Effect of High Pressure on the Diastereoselectivity of Intermolecular All-Carbon Diels-Alder Reactions

Lutz F. Tietze, Marielouise Henrich, Anja Niklaus, Michael Buback

Chemistry - A European Journal · 1999 · 23 citations · 0 references

DOI

Concepts

Abstract

Increased pressure favours the cis adducts in the cyclization of phenylbutadienes 1 with dicyanoethylenes 2 to give cyclohexenes.