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Rhodium(<scp>I</scp>)–sulfonated-bdpp catalysed asymmetric hydrogenation of imines in aqueous–organic two-phase solvent systems
124
Citations
15
References
1991
Year
Chemical EngineeringEngineeringBiochemistryNatural SciencesCoordination ComplexImines ArcSulfonated BdppOrganic ChemistryOrganometallic CatalysisCatalysisRhodium ComplexesChemistryHomogeneous CatalysisMolecular ComplexMolecular CatalysisAsymmetric CatalysisAsymmetric HydrogenationInorganic Compound
The imines ArC(Me)NCH2Ph (Ar = Ph, 2-MeO-C6H4, 3-MeO-C6H4, 4-MeO-C6H4) are hydrogenated to the corresponding amines with extremely high enantioselectivities up to 96% under very mild conditions, using rhodium complexes associated with sulfonated bdpp.
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