Concepedia

Highly Diastereoselective Indium-Mediated Allylation of Chiral Hydrazones

Gregory R. Cook, Bikash C. Maity, Robert B. Kargbo

Organic Letters · 2004 · 63 citations · 20 references

DOI

Concepts

Abstract

The indium-mediated allylation of chiral hydrazones was investigated. Essentially complete diastereoselectivity and quantitative yields were obtained for substrates derived from both aromatic and aliphatic aldehydes. [reaction--see text]

References

20

Indium- and gallium-mediated carbon–carbon bond-forming reactions in organic synthesis

Vijay Nair, Sindu Ros, C. N. Jayan et al. · Tetrahedron · 2004 · 224 citations

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Development of a Highly α-Regioselective Metal-Mediated Allylation Reaction in Aqueous Media:  New Mechanistic Proposal for the Origin of α-Homoallylic Alcohols

Kui‐Thong Tan, Shu‐Sin Chng, Hin‐Soon Cheng et al. · Journal of the American Chemical Society · 2003 · 147 citations

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Enantioselective Synthesis of Homoallylic Amines by Addition of Allylmetal Reagents to Imines Derived from (S)-Valine Esters

Tiziana Basile, Allaye Bocoum, Diego Savoia et al. · The Journal of Organic Chemistry · 1994 · 126 citations

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Highly Stereoselective Intermolecular Radical Addition to Aldehyde Hydrazones from a Chiral 3-Amino-2-oxazolidinone

Gregory K. Friestad, Jun Qin · Journal of the American Chemical Society · 2000 · 106 citations

, , +7

Asymmetric Allylsilane Additions to Enantiopure N-Acylhydrazones with Dual Activation by Fluoride and In(OTf)3 We thank the National Science Foundation (Vermont EPSCoR) and the University of Vermont for generous support.

Gregory K. Friestad, Hui Ding · Angewandte Chemie International Edition · 2001 · 90 citations

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