Concepedia

Crystal Structure of a Silicon-Bridged Anionic Sodocene Complex:  Evidence for Alkene−Na<sup>+</sup> π-Bonding

Sjoerd Harder, Martin Lutz, Stephan J. Obert

Organometallics · 1999 · 14 citations · 12 references

DOI

Concepts

Abstract

The (allyl) 2 Si-bridged Cp 2 Na anion crystallizes as a polymeric chain structure in which Na cations bridge [(allyl) 2 Si(C 5 H 4 ) 2 ] 2 - units. One of the allyl substituents of the Si bridge shows alkene−Na + π-bonding interactions.

References

12

Computational crystallography

B. Winkler · Acta Crystallographica Section A Foundations of Crystallography · 2012 · 705 citations · Full text

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Phosphorus- and arsenic-bridged [1]ferrocenophanes. 1. Synthesis and characterization

Dietmar Seyferth, H.P. Withers · Organometallics · 1982 · 125 citations

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Phosphorus- and arsenic-bridged [1]ferrocenophanes. 2. Synthesis of poly((1,1'-ferrocenediyl)phenylphosphine) oligomers and polymers

H.P. Withers, Dietmar Seyferth, J. D. FELLMANN et al. · Organometallics · 1982 · 108 citations

, , +8

The Crystal Structure of (1, 1′‐ferrocenediyl)diphenylsilane

H. Stoeckli‐Evans, Anthony G. Osborne, Richard H. Whiteley · Helvetica Chimica Acta · 1976 · 72 citations

, , +13

Unusually Strong Interactions Mediated by Both .pi.-.pi. Stacking and CH-.pi. Interactions Present in the Dimer of Nickel(II) Complex Coordinated with n-Butyl-Substituted Salen

Kazuo Miyamura, Akiko Mihara, Takashi Fujii et al. · Journal of the American Chemical Society · 1995 · 69 citations

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