Concepedia

Electrocatalytic reduction of protons to hydrogen by a water-compatible cobalt polypyridyl platform

J.P. Bigi, T.E. Hanna, W. Hill Harman, Alicia Chang, Christopher J. Chang

Chemical Communications · 2009 · 214 citations · 52 references

Concepts

Natural SciencesChemical EngineeringChemistryCatalysisElectrochemistryInorganic ChemistryCatalytic MaterialsCharge Transfer ReactionsCoordination ChemistryElectrochemical SynthesisOxidation-reduction ReactionsSupported CatalystsCobalt CatalysisElectrocatalyst DesignElectrocatalytic ReactorsElectrochemical HydrogenationHydrogen ReductionMetal-assisted Acid-base CatalysisSupported Electrocatalysts

Abstract

A cobalt(ii) complex supported by the new tetradentate polypyridyl ligand PY4 is an electrocatalyst for the reduction of protons to hydrogen and can operate in 50% aqueous media.

References

52

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