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Syntheses, Charge Distribution, and Molecular Second-Order Nonlinear Optical Properties of Push-Pull Bisdithiolene Nickel Complexes
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1998
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Inorganic ChemistryCharge DistributionsOptical MaterialsEngineeringPhysicsOptical PropertiesBisdithiophene NickelNatural SciencesApplied PhysicsNon-linear OpticCoordination ComplexPhysical ChemistryMolecular ComplexNlo PropertiesQuantum ChemistryChemistryInorganic SynthesisCharge Distribution
The second-order nonlinear optical (NLO) properties of some bisdithiophene d8 metal complexes, for example, the donor–acceptor unsymmetrically substituted bisdithiophene nickel(II) complex shown in the Figure, are reported for the first time. The synthesis and characterization of the complexes are described and the relationship between their charge distributions and NLO properties is discussed.