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Base catalytic activity of alkaline earth MOFs: a (micro)spectroscopic study of active site formation by the controlled transformation of structural anions

Pieterjan Valvekens, Dries Jonckheere, Trees De Baerdemaeker, A. V. Kubarev, Matthias Vandichel, Karen Hemelsoet, Michel Waroquier, Véronique Van Speybroeck, Erik Smolders, Diederik Depla,

Chemical Science · 2014 · 65 citations · 24 references

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Concepts

Abstract

The selective decomposition of structural nitrate anions in alkaline earth MOFs generates highly dispersed base sites with catalytic applications.

References

24

Industrial application of solid acid–base catalysts

Kozo Tanabe · Applied Catalysis A General · 1999 · 1.1K citations

, , +6

Structural diversity and chemical trends in hybrid inorganic–organic framework materials

Anthony K. Cheetham, C. N. R. Rao, R.K. Feller · Chemical Communications · 2006 · 1.1K citations

Overview of the Fundamental Reactions and Degradation Mechanisms of NOx Storage/Reduction Catalysts

William S. Epling, L. E. Campbell, Aleksey Yezerets et al. · Catalysis Reviews · 2004 · 889 citations

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Expanding Applications of Metal−Organic Frameworks: Zeolite Imidazolate Framework ZIF-8 as an Efficient Heterogeneous Catalyst for the Knoevenagel Reaction

Uyen P. N. Tran, Ky Khac Anh Le, Nam T. S. Phan · ACS Catalysis · 2011 · 670 citations

, , +21

Amino-based metal-organic frameworks as stable, highly active basic catalysts

Jorge Gascón, U AKTAY, María D. Hernández‐Alonso et al. · Journal of Catalysis · 2008 · 649 citations

, , +6