Publication | Closed Access
A thermally derived and optimized structure from ZIF-8 with giant enhancement in CO<sub>2</sub> uptake
292
Citations
68
References
2014
Year
Materials ScienceInorganic ChemistryChemical EngineeringGiant EnhancementEngineeringCatalytic MaterialSolid-state ChemistryZif-8 CloseThermal CatalysisFunctional MaterialsCatalysisInitial Zif-8ChemistryPost-synthesis Thermal AnnealingCrystallographyCrystal Structure Design
Post-synthesis thermal annealing of ZIF-8 close to its framework decomposition temperature below 550 °C results in a modified structure with highly enhanced and stable cyclic CO<sub>2</sub> adsorption capacity of over 1.5 mmol g<sup>−1</sup> at 25 °C and 1 bar of CO<sub>2</sub>, which is over 100% greater than that of initial ZIF-8.
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