Al–H σ-bond coordination: expanded ring carbene adducts of AlH3 as neutral bi- and tri-functional donor ligands

Abstract

Thermally robust expanded ring carbene adducts of AlH3 have been synthesized with a view to probing their ligating abilities via Al-H σ-bond coordination. While κ(2) binding to the 14-electron [Mo(CO)4] fragment is readily demonstrated, interaction with [Mo(CO)3] results in μ:κ(1),κ(1) and μ:κ(2),κ(2) bridging linkages rather than terminal κ(3) binding.