Intramolecular Ir(I)-Catalyzed Benzylic C−H Bond Amination of<i>ortho</i>-Substituted Aryl Azides - Concepedia

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Intramolecular Ir(I)-Catalyzed Benzylic C−H Bond Amination of<i>ortho</i>-Substituted Aryl Azides

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References

2009

Year

Ke Sun, Rachna Sachwani, Kathleen J. Richert, Tom G. Driver

Organic Letters

Degrees CBiochemistryNatural SciencesOrtho-homobenzyl-substituted Aryl AzidesOrganic ChemistryOrganometallic CatalysisChemistrySynthetic ChemistryAryl Azides

Abstract

Iridium(I) catalyzes the intramolecular benzylic C-H bond amination of ortho-homobenzyl-substituted aryl azides to produce indolines at 25 degrees C.