Journal of Geophysical Research Atmospheres · 1992 · 102 citations · 42 references
Natural SciencesChemistryEnvironmental SciencesAir PollutionAtmospheric ChemistryEnvironmental ChemistryAtmospheric Oxidation ProcessesAtmospheric Radical ChemistryOxidation ReactionsReactive Oxygen SpeciesRedox ChemistryRedox ProcessesAtmospheric Oxidation MechanismsOxidant ChemistryPeroxy IntermediatesPeroxy Radical ChemistryPhotostationary StateReactive Oxygen Species ChemistryReactive Oxygen Species MeasurementTropospheric Trace Gases
The concentrations of the HO 2 ‐RO 2 species measured during July 11, 1990, in the ROSE (Rural Oxidants in the Southern Environment) study in Alabama are compared to those expected in theory from calculations based upon detailed hourly measurements of a variety of trace gases including the hydrocarbons, NO, NO 2 , carbonyl compounds, CO, PAN (peroxyacetylnitrate) and calculated j O 3 values. The measurements are also compared with the [HO 2 ] + [RO 2 ] as estimated from deviations from the NO 2 + hv (+O 2 ) ⇄ NO + O 3 photostationary state. Within the error of the measurements all of the data appear to be in reasonable accord.
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Models and observations of the impact of natural hydrocarbons on rural ozone
M. Trainer, E. J. Williams, D. D. Parrish et al. · Nature · 1987 · 525 citations