Publication | Closed Access
Si<sub>6</sub>H<sub>6</sub>: Is the Aromatic Structure the Most Stable One?
67
Citations
28
References
1986
Year
Relative StabilitiesEngineeringNatural SciencesChemical BondSiliceneOrganic ChemistryPhysical ChemistrySi6h6 IsomersQuantum ChemistryChemistryAromatic StructureHexasilabenzene 2
No! Calculations of the relative stabilities of Si6H6 isomers give a completely different picture from what one is used to in carbon chemistry. Hexasilaprismane 1 is markedly more stable than hexasilabenzene 2, although the resonance energy of the π-electron system of 2 is only about 30% less than that of benzene.
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