Revisiting The Second Law of Energy Degradation and Entropy Generation: From Sadi Carnot's Ingenious Reasoning to Holistic Generalization

Abstract

Sadi Carnot's ingenious reasoning of reversible cycles (1824) laid foundations for The Second Law before The First Law of energy conservation was even known (Joule 1843) and long before Thermodynamic concepts were established in 1850s. A century later, Bridgman (1941) 'complained' that "there are almost as many formulations of The Second Law as there have been discussions of it." Even today, The Second Law remains so obscure, due to the lack of its comprehension, that it continues to attract new efforts at clarification, including this one.