Concepedia

The Isolobal Analogy “”

Peter Hofmann, Helmut R. Schmidt

Angewandte Chemie International Edition in English · 1986 · 21 citations · 7 references

DOI

Concepts

Abstract

A useful guideline for planning syntheses, in particular of new di‐ or polynuclear complexes containing d 6 ‐CpM(CO) 3 groups (MCr, Mo, W), could be the isolobal realtionship between these groups and the ubiquitous C 5 H ligand. This relationship is demonstrated on the basis of qualitative considerations, MO calculations and MO contour diagrams, and on the basis of the known structures of complex molecules containing CpM(CO) or Cp ⊖ groups.

References

7

Orbital Interactions in Chemistry

K. N. Houk · Organometallics · 1986 · 831 citations

, , +11

Dinuclear, 18-electron species having a triplet ground state: isolation, characterization, and crystal structure of photogenerated (.eta.5-C5Me5)2Fe2(.mu.-CO)3

Josephine Paw Blaha, Bruce E. Bursten, John C. Dewan et al. · Journal of the American Chemical Society · 1985 · 124 citations

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Organometallic complexes with metal-metal bonds. 19. Comparison of two strategies towards the syntheses of platinum mixed-metal clusters. Reactivity of linear M-Pt-M and Mn-Pt-Mn complexes. X-ray crystal structures of Pt2M2(.eta.5-C5H5)2(.mu.3-CO)2(.mu.-CO)4(PEt3)2 with M = Cr, Mo, and W

Robert Bender, Pierre Braunstein, Jean Marc Jud et al. · Inorganic Chemistry · 1984 · 78 citations

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Organometallic complexes with metal-metal bonds. 18. Syntheses of tetrametallic planar, triangulated mixed-metal palladium clusters. X-ray crystal structures of Pd2M2(.eta.5-C5H5)2(.mu.3-CO)2(.mu.2-CO)4(PEt3)2 with M = Cr, Mo, and W

Robert Bender, Pierre Braunstein, Jean Marc Jud et al. · Inorganic Chemistry · 1983 · 73 citations

, , +12

Relevance to Synthetic Polynuclear Chemistry of Novel μ<sub>3</sub>-Coordination Modes for the Anions Ph<sub>2</sub>PCHCOOC<sub>2</sub>H<sub>2</sub><sup>-</sup> and Mo(CO)<sub>3</sub>Cp<sup>-</sup>. Synthesis and X-ray Structure of Pd(8-mq)Br(Ph<sub>2</sub>PCH<sub>2</sub>COOC<sub>2</sub>H<sub>5</sub>), {[Pd(8-mq)]<sub>3</sub>(μ<sub>3</sub>-Ph<sub>2</sub>PCHCOOC<sub>2</sub>H<sub>5</sub>)(μ<sub>3</sub>-OH)}PF<sub>6</sub>, and {[Pd(8-mq)]<sub>3</sub> [μ<sub>3</sub>-Mo(CO)<sub>3</sub>Cp](μ<sub>3</sub>-Cl)}BF<sub>4</sub>

Pierre Braunstein, Jean Fischer, Dominique Matt et al. · Journal of the American Chemical Society · 1984 · 56 citations

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